OBJECTIVE：To establish a method for the determination of 7 residual solvents （ethanol， n-hexane， benzene， toluene， xylene， styrene， divinylbenzene） in Liuwei dihuang glycoside. METHODS： The column was DB-624 capillary column， carrier gas was nitrogen， flow rate was 5.0 ml/min； detector was a hydrogen flame ionization detector with temperature of 250 ℃ （programmed temperature）； equilibrium temperature was 80 ℃， sample loop temperature was 90 ℃， and transfer line temperature was 100 ℃； the equilibrium time of vial heating was 30 min， sample loop filling time was 0.05 min， injection time was 1.0 min； the carrier gas pressure was 95 kpa， and the vial pressure was 60 kpa. RESULTS： The linear range was 25-500 μg/ml for ethanol（r＝0.998 7）， 0.025-10 μg/ml for n-hexane （r＝0.998 8），0.025-10 μg/ml for benzene （r＝0.999 9）， 0.1-40 μg/ml for toluene（r＝1.000 0）， 0.25-100 μg/ml for xylene（r＝0.999 9），0.5-500 μg/ml for styrene（r＝1.000 0） and 0.5-500 μg/ml for divinylbenzene （r＝1.000 0）； RSDs of precision， stability and reproducibility tests were lower than 4％； recoveries were 99.60％-102.70％ （RSD＝1.08％，n＝9），90.70％-100.30％（RSD＝4.51％，n＝9），100.10％-109.80％（RSD＝3.82％，n＝9）， 99.50％-110.00％ （RSD＝4.40％，n＝9），100.00％-109.10％（RSD＝3.50％，n＝9）， 93.40％-102.30％（RSD＝3.73％，n＝9） and 99.70％-101.70％ （RSD＝0.79％，n＝9）， respectively； the low limits of detection were 1.000， 0.025，0.025，0.025，0.100，0.025，0.250 μg/ml respectively. CONCLUSIONS： The method is simple， stable and reproducible， and can be used for the determination of residual solvents （ethanol， n-hexane， benzene， toluene， xylene， styrene， divinylbenzene） in Liuwei dihuang glycoside.